Excess heat capacity and entropy of mixing along the chlorapatite–fluorapatite binary join     

Edgar Dachs  Daniel Harlov  Artur Benisek 《Physics and Chemistry of Minerals》2010,37(9):665-676

The heat capacity at constant pressure, C _p, of chlorapatite [Ca₅(PO₄)₃Cl – ClAp], and fluorapatite [Ca₅(PO₄)₃F – FAp], as well as of 12 compositions along the chlorapatite–fluorapatite join have been measured using relaxation calorimetry [heat capacity option of the physical properties measurement system (PPMS)] and differential scanning calorimetry (DSC) in the temperature range 5–764 K. The chlor-fluorapatites were synthesized at 1,375–1,220°C from Ca₃(PO₄)₂ using the CaF₂–CaCl₂ flux method. Most of the chlor-fluorapatite compositions could be measured directly as single crystals using the PPMS such that they were attached to the sample platform of the calorimeter by a crystal face. However, the crystals were too small for the crystal face to be polished. In such cases, where the sample coupling was not optimal, an empirical procedure was developed to smoothly connect the PPMS to the DSC heat capacities around ambient T. The heat capacity of the end-members above 298 K can be represented by the polynomials: C _p^ClAp = 613.21 − 2,313.90T ^−0.5 − 1.87964 × 10⁷ T ⁻² + 2.79925 × 10⁹ T ⁻³ and C _p^FAp = 681.24 − 4,621.73 × T ^−0.5 − 6.38134 × 10⁶ T ⁻² + 7.38088 × 10⁸ T ⁻³ (units, J mol⁻¹ K⁻¹). Their standard third-law entropy, derived from the low-temperature heat capacity measurements, is S° = 400.6 ± 1.6 J mol⁻¹ K⁻¹ for chlorapatite and S° = 383.2 ± 1.5 J mol⁻¹ K⁻¹ for fluorapatite. Positive excess heat capacities of mixing, ΔC _p^ex, occur in the chlorapatite–fluorapatite solid solution around 80 K (and to a lesser degree at 200 K) and are asymmetrically distributed over the join reaching a maximum of 1.3 ± 0.3 J mol⁻¹ K⁻¹ for F-rich compositions. They are significant at these conditions exceeding the 2σ-uncertainty of the data. The excess entropy of mixing, ΔS ^ex, at 298 K reaches positive values of 3–4 J mol⁻¹ K⁻¹ in the F-rich portion of the binary, is, however, not significantly different from zero across the join within its 2σ-uncertainty.  相似文献   

A ternary feldspar-mixing model based on calorimetric data: development and application   总被引：8，自引：0，他引：8  

Artur Benisek  Edgar Dachs  Herbert Kroll 《Contributions to Mineralogy and Petrology》2010,160(3):327-337

A mixing model for high structural state ternary feldspars in the NaAlSi₃O₈–KAlSi₃O₈–CaAl₂Si₂O₈ system is presented based exclusively on calorimetric and volumetric measurements. Comparisons with existing mixing models, which are based on phase-equilibrium experiments, reveal distinct differences. The incorporation of K into Ca-rich plagioclase and of Ca into K-rich alkali feldspar is more strongly limited by our calorimetry-based model, whereas the stability field of Na-rich feldspars is broadened. Natural feldspar assemblages from well-studied magmatic and high-grade metamorphic rocks (i.e. a teschenite sill in Scotland, the Klokken syenogabbro in Greenland, and a granulite-facies metapelite in Sri Lanka) were used to test the mixing models. It was found that the new model largely eliminates discrepancies between observed and predicted feldspar compositions that were present in earlier attempts. The reasons for the problems associated with phase-equilibrium based mixing models are discussed.  相似文献   

Relations between assemblages of carpological remains and modern vegetation in a shallow reservoir in southern Poland     

Artur Szymczyk 《Journal of Paleolimnology》2012,48(3):503-516

This paper explores relations between assemblages of carpological remains and vegetation in and around a small, shallow reservoir in southern Poland. The study was conducted from 2006 to 2008. Quantity and distribution of species in the reservoir were recorded annually during the growing season. In October 2008, 40 samples of surface sediment (top 2?cm) were collected along transects at 10?m intervals. Samples of 100?cm³ were prepared for analysis of plant macroremains. Assemblages of carpological remains generally reflect local vegetation well. In some cases, however, even analysis of numerous samples failed to fully capture the species composition or reflect plant ratios in the parent phytocenosis. Reasons for this include factors that affect seed production, transport and fossilization, which differ among species. Among the best-represented macroremains were plants of the rush phytocenosis. In analysed samples, macroremains of 68.8?% of extant rushes were identified. Sixty percent of submerged and floating-leaf taxa were found in carpological samples, whereas 26.7?% of the trees and bushes were represented in sediment deposits. Species composition of phytocenoses in the reservoir and in surrounding areas was best reflected by macroremains from the nearby reed bed. Numbers of diaspores of Mentha aquatica, Hippuris vulgaris and Carex reflected well their relative abundance in phytocenoses. Chara sp., Juncus inflexus and Eupatorium cannabinum were overrepresented, whereas Typha latifolia and Sparganium minimum were poorly represented in relation to contemporary plant cover. There were no diaspores of Phragmites australis, which dominates the contemporary reed bed. Besides the shape of a reservoir, the key factor influencing diaspore numbers is distribution of plant cover. In many cases, single diaspores (Potentilla erecta, Myosotis scorpioides, Lythrum salicaria, Scutellaria galericulata), or higher concentrations (Hippuris vulgaris, Mentha aquatica, Eleocharis palustris, Schoenoplectus tabernaemontani, Chara sp.) reflected well the location of parent vegetation. The findings indicate that carpological remains in sediments can be an important source of information about plants in and around lakes. They generally reflect well local vegetation and in some cases may be used to identify taxa that dominated in the past.  相似文献   

Thermodynamic mixing behavior of synthetic Ca-Tschermak–diopside pyroxene solid solutions: I. Volume and heat capacity of mixing     

Katja Etzel  Artur Benisek  Edgar Dachs  Lado Cemič 《Physics and Chemistry of Minerals》2007,34(10):733-746

The unite cell parameters and heat capacities of a series of synthetic clinopyroxenes on the join Ca-Tschermak (CaTs)−diopside (Di) were measured using X-ray powder diffraction and calorimetric methods, respectively. The volume of mixing at 298 K shows a negative asymmetric deviation from ideality. A two-parameter Margules fit to the data yields W _CaTs−Di ^V = −0.29 ± 0.11 cm³ mol⁻¹ and W _Di−CaTs ^V = −1.14 ± 0.14 cm³ mol⁻¹. Heat capacities were determined between 5 and 923 K by heat-pulse at 5−302 K and differential-scanning calorimetry at 143−923 K. The precision of the low and high temperature C _p data is better than ±1%. Polynomials of the form C _p = a + bT ^−1/2 + cT ⁻² + dT ⁻³ were fitted to the C _p data in the temperature range between 250 and 925 K. Thermal entropy values [S ₂₉₈ − S ₀] and [S ₉₀₀ −S ₀] as well as enthalpies [H ₂₉₈ − H ₀] and [H ₉₀₀ − H ₀] were calculated for all members of the solid solution series. No significant deviation from ideal mixing behavior was observed.  相似文献   

Archaeological objects in loesses recognized by GPR research at the site Karmanowice,Poland     

Artur Poręba  Wacław M. Zuberek  Jolanta Nogaj-Chachaj  Andrzej Kotyrba  Sławomir Siwek 《Acta Geophysica》2007,55(4):640-651

The aim of the research was to examine subsurface soil layers with the use of the Ground Penetrating Radar (GPR) method. Neolithic archaeological post in Karmanowice was examined. On the basis of earlier geophysical researches and archaeological premises, eight measurement profiles had been chosen. Ground Penetrating Radar system with antenna of 500 MHz frequency was applied. The measurements were made with 30 and 60 ns time windows. The results were shown as the GPR sections. The analysis of the obtained results allowed us to outline anomalies connected with the appearance of archaeological objects in subsurface soil layers. The border between the anthropogenically changed upper layer and undisturbed loess was established, and the sections of slope wash layers were designated. Anomalies were confirmed by digging and test drillings. Additionally, 2D resistivity imaging method was used for verification of specific anthropogenic anomalies.  相似文献   

Changes of Ground-Water Quality Near a Well Undergoing Acid Treatment     

Wlodzimierz Wojcik  Artur Wieczysty 《Ground water》1986,24(6):724-727

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On rigid foundations subjected to seismic waves     

Artur L. Pais  Eduardo Kausel 《地震工程与结构动力学》1989,18(4):475-489

In the analysis of structural foundations for seismic loads, it is customary to distinguish two types of soil-structure interaction effect: kinematic interaction (or wave passage), and inertial interaction. The former refers to the phenomenon of wave scattering, which occurs because the foundation is much stiffer than the surrounding soil and cannot accommodate to its distortions. Inertial interaction, on the other hand, is caused by feedback of kinetic energy of the structure into the soil. This paper is concerned only with the first phenomenon. The rigorous analysis of rigid, embedded foundations subjected to seismic disturbances requires, in general, substantial computational effort. Indeed, a typical analysis would normally require models with finite elements and/or boundary elements. Although such methods may be used to find an accurate solution to the problem of kinematic interaction, their use is not always warranted, given the many uncertainties involved and the multitude of assumptions that must be considered. Hence, approximate solutions are attractive for this problem. One such approximate method is the remarkably simple algorithm proposed by Iguchi.³ This paper presents first an appraisal of this method by way of a comparison with accurate numerical solutions for cylindrical foundations; next the algorithm is applied to rectangular (prismatic) foundations. It is found that Iguchi's method gives results that are adequate for engineering purposes, even if not entirely accurate.  相似文献   

Computation of analytical partial derivatives of phase and group velocities for Rayleigh waves with respect to structural parameters     

Ludvík Urban  Artur Cichowicz  Franco Vaccari 《Studia Geophysica et Geodaetica》1993,37(1):14-36

Summary The analytical expressions used to compute the partial derivatives of phase and group velocity of Rayleigh waves with respect to the P- and S-wave velocity and the density are derived and the related computer code is developed. The results of the analytical computations were satisfactorily tested against numerically determined values. Several examples of partial derivatives for a given structural model are presented.  相似文献   

Approximate formulas for dynamic stiffnesses of rigid foundations   总被引：3，自引：0，他引：3  

Artur Pais  Eduardo Kausel 《Soil Dynamics and Earthquake Engineering》1988,7(4):213-227

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Petrology,geochemistry, and geochronology of Paleoproterozoic volcanic and granitic rocks (1.89–1.88 Ga) of the Pitinga Province,Amazonian Craton,Brazil     

J. Maximino T.M. Ferron  Artur C. Bastos Neto  Evandro F. Lima  Lauro V.S. Nardi  Hilton T. Costi  Ronaldo Pierosan  Maurício Prado 《Journal of South American Earth Sciences》2010,29(2):483-497

This paper presents geochemical, petrographic, and geochronological data on the Uatumã magmatism in the Pitinga Province, where it is represented by volcanic rocks from the Iricoumé Group and granitic rocks from the Mapuera Suite. The Iricoumé Group (1.89–1.88 Ga) is constituted of the Divisor Formation (intermediate volcanic rocks), Ouro Preto Formation (acid effusive rocks), and Paraiso Formation (acid crystal-rich ignimbrites, surge deposits, and basic rocks). The volcanic sequence is intruded by granitoids from the Mapuera Suite (1.88 Ga), mainly represented by monzogranites and syenogranites. Structural and field relations suggest that caldera complex collapse controlled the emplacement of volcanics and granitoids of the Mapuera Suite. Subsequent structure reactivations allowed the younger Madeira Suite (1.82–1.81 Ga) to be emplaced in the central portion of the caldera complex. The felsic Iricoumé magmatism is mainly composed of rhyolites, trachydacites and latites, with SiO₂ contents between 64 wt% and 80 wt%. The plutonic rocks from the Mapuera Suite present SiO₂ between 65 wt% and 77 wt%. Volcanic and granitic rocks present identical geochemical characteristics and that is attributed to their co-magmatic character. The felsic volcanic rocks and granites are metaluminous to slightly peraluminous and show affinity with silica-saturated alkaline series or with A-type magmas. They have Na₂O + K₂O between 6.6% and 10.4%, FeO^t/(FeO^t + MgO) varying between 0.76 and 0.99, Ga/Al ratios between 1.5 and 4.9, like typical A-type rocks; and plot in the within-plate or post-collisional fields in the (Nb + Y) vs. Rb diagram. The Nb/Y ratios indicate that these rocks are comparable to A2-type granites. This magmatism can be related to the (i) potassic alkaline series, with low Sr content in the felsic rocks explained by plagioclase fractionation at low pressure and high temperature or, alternatively, (ii) a bimodal association where magma had high crustal influence. The similarity of the Iricoumé felsic magmatism with A2-type granitoids and their high ETRL/Nb ratios suggest its relation with mantle sources previously modified by subduction, probably in a post-collision environment. Alternatively, this can be interpreted as bimodal within-plate magmatism with contamination by crustal melts. In this context, the extreme F, Nb and Zr enrichment of Madeira Suite could be explained by the presence of a thin crust which favored the presence and continuity of convective systems in the upper mantle.  相似文献